STEREOSELECTIVE SYNTHESIS OF N,N'-DIACYL-p-MENTHANE-1,8-DIAMINES

Article abstract of DOI:10.1007/BF00598074

It has been shown that the interaction of terpin hydrate with various nitriles under the conditions of the Ritter reaction takes place stereoselectively and leads to the formation of a mixture of isomeric cis- and trans-N,N'-diacyl-p-menthane-1,8-diamines in a ratio of 1:4.The structures of the products have been shown by 1H and 13C spectroscopy.