The reaction of isosteric isobutyl(isopropoxy)silanes iBun(iPrO)3-nSiH (n = 0-3) with allyl bromide in the presence of platinum compounds

DOI: 10.1016/0022-328X(90)80197-8

Source and publish data:

Journal of Organometallic Chemistry p. 187 - 193 (1990)

Update date:2022-07-29

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Authors:

Pikies, J.

Wojnowski, W.

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Article abstract of DOI:10.1016/0022-328X(90)80197-8

The isosteric silanes ⁱBun(ⁱPrO)3-nSiH react with allyl bromide to yield the corresponding bromides ⁱBun(ⁱPrO)3-nSiBr.The reactivities of the silanes fall in the sequence: ⁱBu(ⁱPrO)2SiH <*> ⁱBu2(ⁱPrO)SiH > (ⁱPrO)3SiH > ⁱBu3SiH which can be accounted for in terms of the anomeric effects at the silicon atom.

Full text of DOI:10.1016/0022-328X(90)80197-8

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