Journal of Organometallic Chemistry p. 187 - 193 (1990)
Update date:2022-07-29
Topics:
Pikies, J.
Wojnowski, W.
The isosteric silanes iBun(iPrO)3-nSiH react with allyl bromide to yield the corresponding bromides iBun(iPrO)3-nSiBr.The reactivities of the silanes fall in the sequence: iBu(iPrO)2SiH <*> iBu2(iPrO)SiH > (iPrO)3SiH > iBu3SiH which can be accounted for in terms of the anomeric effects at the silicon atom.
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