Journal of the Chemical Society. Chemical communications p. 943 - 944 (1994)
Update date:2022-08-05
Topics: Synthesis Investigation
Church, Nicola J.
Young, Douglas W.
Stereospecifically deuteriated samples of D-prop-2-ynylglycine 1 are synthesised by reaction of the labelled aziridines 13 with a carbon nucleophile followed by deprotection; incubation of these samples with D-amino acid oxidase indicates that, in formation of the lactone 5, deprotonation at C-3 is non-stereospecific, strongly supporting non-enzymatic deprotonation as a key step in the formation of this compound.
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