A Ruthenium(IV) Oxo Complex that contains a Tertiary Diamine Ligand

DOI: 10.1039/DT9900000967

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Journal of the Chemical Society, Dalton Transactions p. 967 - 970 (1990)

Update date:2022-09-26

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Authors:

Ho, Clare

Che, Chi-Ming

Lau, Tai-Chu

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Article abstract of DOI:10.1039/DT9900000967

The complex 2+ (terpy = 2,2':6',2''-terpyridine, tmen = N,N,N',N'-tetramethylethylenediamine) and its corresponding oxo complex have been prepared.Their spectral properties and redox properties in aqueos solution were investigated.Evidence for two one-electron redox processes has been obtained for the Ru^IV-Ru^III and Ru^III-Ru^II couples.The reaction of the new ruthenium(IV) oxo species with olefins have been found to proceed with second-order kinetics, rate = k₂IV> where k₂ = (3.3 +/- 0.3) x 10^-3 and (2.0 +/- 0.2) x 10^-2 dm³mol^-1s^-1 at 25 deg C for norbornene and styrene respectively

Full text of DOI:10.1039/DT9900000967

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