Journal of the American Chemical Society p. 648 - 649 (2003)
Update date:2022-08-03
Topics: Transmetallation Oxidative Addition Reductive Elimination
Pei, Tao
Wang, Xiang
Widenhoefer, Ross A.
Reaction of 5,5-dimethyl-8-nonene-2,4-dione catalyzed by PdCl2(CH3CN)2 (5 mol %) in the presence of CuCl2 (2.5 equiv) at room temperature for 3 h formed 2-acetyl-3,6,6-trimethyl-2-cyclohexenone in 96% isolated yield. Palladium-catalyzed intramolecular oxidative alkylation tolerated a range of substitution and was applicable to the synthesis of spirobicyclic compounds and to the cyclization of ζ-alkenyl β-keto esters. Copyright
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