Journal of Organic Chemistry p. 6350 - 6355 (2013)
Update date:2022-08-04
Topics:
Li, Ke
Hu, Naifu
Luo, Renshi
Yuan, Weicheng
Tang, Wenjun
A novel ruthenium catalyst on the basis of a chiral monophosphorus ligand is efficient for the asymmetric addition of arylboronic acids to aryl aldehydes, providing a series of chiral diarylmethanols in excellent yields and enantioselectivities (up to 92% ee). Preliminary study has shown that this process is catalyzed by a Ru complex with a single monophosphorus ligand.
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