Journal of Fluorine Chemistry p. 219 - 225 (1990)
Update date:2022-09-26
Topics:
Freed, Bethany K.
Middleton, W. J.
Several examples of (α-perfluoroheptyl-β,β-dicyanovinyl)aminostyrenes (3), a novel class of perfluorocarbon-soluble dyes, were prepared by the reaction of 2-chloro-1,1-dicyano-2-(perfluoroheptyl)ethylene (2) with aromatic amines.The ethylene 2 was prepared from methyl perfluorooctanoate, malononitrile, and phosphorous pentachloride.The λmax for perfluorohexane solutions of the dyes ranges from 419 nm for the dye prepared from N-phenylmorpholine to 490 nm for the dye prepared from julolidine.
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