Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 741 - 745 (1990)
Update date:2022-08-05
Topics: IR spectroscopy Regioselectivity Yield Catalyst Derivatives Steric hindrance Nucleophilic substitution TLC (thin-layer chromatography) NMR (nuclear magnetic resonance) Phenols Leaving group Workup Reaction Mechanism Solvent Effects Activation Energy Electrophilic Aromatic Substitution Byproduct Sulfenylation Trifluoromethyl group (–CF?)
Sizov, A. Yu
Kolomiets, A. F.
Fokin, A. V.
In the absence of a catalyst, α-trifluoromethyl-β-chloroethylsulfenyl chloride reacts electrophilically with ortho-para-substituted phenols bearing substituents of the first type.The reaction conditions are determined by the C-nucleophilic properties of t
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