Tetrahedron Letters p. 1853 - 1856 (1990)
Update date:2022-09-26
Topics:
Kpegba, Kafui
Metznei, Patrick
Reacion of titanium enethiolates with α-unsaturated ketones leads selectively to 3-hydroxy 4-saturated alkanedithioates, arising from a 1,2-carbon-addition, whereas aluminum enethiolates give oxoketene dithioacetals, from exclusove 1,4-sulphur-addition. Reaction of titanium enethiolates with α-unsaturated ketones leads selectively to 3-hydroxy 4-unsaturated alkanedithioates, arising from a 1,2-carbon-addition, whereas aluminium enethiolates give oxoketene dithioacetals, from exclusive 1,4-sulphur-addition. (Chemical Equation Presented).
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Doi:10.1007/s10593-020-02623-6
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