Application of AMPP-Pd catalysts in an unusual asymmetric allylic coupling reaction of 1-trimethylsilyl vinyl magnesium bromide

DOI: 10.1016/S0040-4039(00)94338-7

Source and publish data:

Tetrahedron Letters p. 77 - 80 (1990)

Update date:2022-07-31

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Authors:

Fotiadu, Frederic

Cros, Philippe

Faure, Bruno

Buono, Gerard

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Article abstract of DOI:10.1016/S0040-4039(00)94338-7

Unusual palladium catalyzed allylation of a silylated Grignard reagent by cyclohexenyl acetate gives in high yields a versatile synthon, 3-(1-trimethyisilyl vinyl) cyclohexene; use of chiral AMPP ligands results in e.e. up to 33 %.

Full text of DOI:10.1016/S0040-4039(00)94338-7

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