Tetrahedron p. 1885 - 1898 (1990)
Update date:2022-07-30
Topics:
Sarkar, Tarun K.
Ghosh, Sunil K.
Satapathi, Tushar K.
The synthesis of (E)-allyltrimethylsilanes by regio- and stereocontrolled pathways is described based on the preference for Krief-Reich elimination over silicon-controlled rearrangement in β-seleno-γ-silyl alcohols, readily available from α-selenoaldehydes, 10 - 12.Usefulness of this protocol for the introduction of the allylsilane function α to the carbonyl group in cycloalkanones as well as for the preparation of unsymmetrically substituted allylsilanes is also reported.
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Doi:10.1039/c1cc15628d
(2012)Doi:10.1007/BF00472554
(1990)Doi:10.1016/S0040-4039(00)94666-5
(1990)Doi:10.1039/c8cc03635g
(2018)Doi:10.1002/adsc.201000679
(2011)Doi:10.1039/J19660000410
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