Tetrahedron Letters p. 2661 - 2664 (1990)
Update date:2022-07-30
Topics:
Dellaria, Joseph F.
Sallin, Kevin J.
A new synthesis of α-substituted primary allylic amines through the in situ generation and trapping of an ylide from the reaction of an N-acyl aziridine, triphenylphosphine, and an aldehyde in refluxing isopropanol is reported.These compounds can be prepared enantioselectively (> 94.6percent ee) by employing a chiral nonracemic N-acyl aziridine.
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Doi:10.1002/cjoc.201190064
(2011)Doi:10.1016/j.tet.2011.01.089
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