Tetrahedron p. 3419 - 3430 (1990)
Update date:2022-08-04
Topics:
Barton, Derek H. R.
Sas, Woijciech
On photolysis with tungsten light, the acyl derivatives of N-hydroxy-2-thiopyridone afford carbon radicals which readily add to quinones.In the case of benzoquinone radical addition is followed by 2-thiopyridyl transfer to afford adducts of type 4.Two different procedures were developed for the conversion of type 4 compounds into hindered quinones of type 7.
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