Lewis acid-catalysed rearrangement of myo-inositol orthoformate derivatives

DOI: 10.1016/0008-6215(92)85043-Y

Source and publish data:

Carbohydrate Research p. 117 - 130 (1992)

Update date:2022-07-29

Topics:

Authors:

Gilbert, Ian H.

Holmes, Andrew B.

Pestchanker, Mauricio J.

Young, Rodney C.

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Article abstract of DOI:10.1016/0008-6215(92)85043-Y

Reduction of 2,4,6-tri-O-benzyl-DL-myo-inositol 1,3,5-orthoformate (1) with di-isobutylaluminium hydride gave 2,4,6-tri-O-benzyl-1,3-O-methylene-DL-myo-inositol (2), whereas reaction with trimethylaluminium gave 2,4,6-tri-O-benzyl-1,5-O-ethylidene-DL-myo-

Full text of DOI:10.1016/0008-6215(92)85043-Y

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