Synthesis and structural studies of tripodal and planar (-) intramolecular coordination systems involving pyrazole donor groups, including oxidative addition of an aryl-bromine bond to platinium(II). Crystal structures of <PtClMe2<(pz)2CR(CH2)-N,N'

Article abstract of DOI:10.1016/0022-328X(90)85417-W

The complex 2 undergoes oxidative addition reactions with chloro-2,2-bis(pyrazol-1-yl)propanes and 2,6-(pzCH2)2C6H3Br to form platinum(IV) complexes PtClMe2<(pz)2CR(CHX)-N,N',C''> and PtBrMe2<2,6-(pzCH2)2C6H3-N,N',C''¹>, respecti