Bisdihydrogenhydridoiron(II) Tetraphenylborate as a Model for the Function of Nitrogenases

DOI: 10.1039/DT9930003041

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3041 - 3050 (1993)

Update date:2022-09-26

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Authors:

Hills, Adrian

Hughes, David L.

Jimenez-Tenorio, Manuel

Leigh, G. Jeffery

Rowley, Adrian T.

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Article abstract of DOI:10.1039/DT9930003041

The trihydride complex (+) (dmpe = Me2PCH2CH2PMe2) is best represented as (+), with the H-H separation in the H2 being ca. 0.81 Angstroem.The H2 can be replaced by N2, CO, MeCN, MeNC and C2H4.The dinitrogen complex (+) may be deprotonated to yield the solution-stable, trigonal-bipyramidal species , which can be reprotonated by HCl to yield , N2, H2 and NH3.The crystal structures of BPh4 and BPh4 have been determined.

Full text of DOI:10.1039/DT9930003041

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