Tetrahedron Letters p. 2407 - 2410 (1990)
Update date:2022-07-29
Topics:
Yamada, Haruo
Shimizu, Katsuya
Nisar, Mohammed
Takahashi, Takashi
Tsuji, Jiro
Synthesis of 1-acetyl-8-methylhydrindan-5-one (3) by the conjugate addition-enolate protonation of the 3-alkyl-2-methyl-1-acetylcyclopentene 1 followed by the cyclization of the cyanhydrin ether, and discussions for the diastereoselectivity in the enolate protonation based on MM2 calculations are presented.
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(2001)Doi:10.1016/j.bmc.2011.01.032
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(2010)Doi:10.1007/BF00809536
(1990)