NEW SYNTHETIC INTERMEDIATE FOR TRANS-8-METHYLHYDRINDANONES

DOI: 10.1016/S0040-4039(00)97374-X

Source and publish data:

Tetrahedron Letters p. 2407 - 2410 (1990)

Update date:2022-07-29

Topics:

Authors:

Yamada, Haruo

Shimizu, Katsuya

Nisar, Mohammed

Takahashi, Takashi

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)97374-X

Synthesis of 1-acetyl-8-methylhydrindan-5-one (3) by the conjugate addition-enolate protonation of the 3-alkyl-2-methyl-1-acetylcyclopentene 1 followed by the cyclization of the cyanhydrin ether, and discussions for the diastereoselectivity in the enolate protonation based on MM2 calculations are presented.

Full text of DOI:10.1016/S0040-4039(00)97374-X

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