Canadian Journal of Chemistry p. 1913 - 1919 (1997)
Update date:2022-07-29
Topics:
Iranpoor, Nasser
Tamami, Bahman
Niknam, Khodabakhsh
Iodine and iodine supported on polyvinylpyrrolidone (betadine) have been used as catalysts for ring opening of epoxides and as reagent for ring-opening dimerization of thiiranes in alcohols, water, and acetic acid. The reactions occur with high regio-, chemo-, and stereoselectivity. The reaction of R-(+)-styrene oxide with I2 supported on PVP in methanol was found to be very stereospecific and the product was isolated in 93% ee.
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