Silylstannylation of ethyl diazoacetate with novel silylstannyl triflates

DOI: 10.1016/0022-328X(90)85054-3

Source and publish data:

Journal of Organometallic Chemistry p. 289 - 294 (1990)

Update date:2022-08-02

Topics:

Authors:

Fronda, Antonio

Maas, Gerhard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)85054-3

Reaction of Ph2^tBuSiSnMe3 or ⁱPr3SiSnMe3 with triflic acid (CF3SO3H; TfOH) at -40 deg C yields the first silylstannyl triflates, Ph2^tBuSiSnMe2OTf and ⁱPr3SiSnMe2OTf.The former triflate is thermally unstable above 0 deg C, but the latter has been isolated as a thermally stable crystalline solid.Both triflates can be used for efficient silylstannylation of ehtyl diazoacetate.

Full text of DOI:10.1016/0022-328X(90)85054-3

Products guided by the article

Product name:(t-butyldiphenylsilyl)dimethylstannyl trifluoromethanesulfonate

Cas No:130481-09-3

R&D Labs maybe for 130481-09-3

zhangjiagang bonded areas banggao co;ltd

website:http://www.shunchangchem.com

Contact:0086-13921972933

Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province
X.T.Y Environ-Tech Co.,Ltd

Contact:+86-310-7092106

Address:Quzhou Modern & New Industrial Park, Handan, Hebei 057250, China
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Shanghai PotentPharm Science and Technology Co.,Ltd

Contact:86-021-51969655

Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China

Relevant to this article

The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines

Doi:10.1016/S0040-4039(99)00810-2
(1999)
Stereoselective total synthesis of (±)-peribysin e

Doi:10.1021/jo2021604
(2012)
Total synthesis of (+)-monomorine I via asymmetric α-ketonic cleavage of 8-azabicyclo[3.2.1]octan-3-one

Doi:10.1248/cpb.38.2072
(1990)
C-Arylglycosylation of Unprotected Free Sugar

Doi:10.1039/c39920001641
(1992)
Turnagainolides A and B, cyclic depsipeptides produced in culture by a Bacillus sp.: Isolation, structure elucidation, and synthesis

Doi:10.1021/np200033y
(2011)
Tuning the regio- and stereoselectivity of C-H activation in n-octanes by cytochrome P450 BM-3 with fluorine substituents: Evidence for interactions between a C-F bond and aromatic π systems

Doi:10.1002/chem.201003631
(2011)

Article Doi