REARRANGEMENTS OF OPTICALLY ACTIVE CYCLOPROPYL ALLYL ESTERS BY LEWIS ACIDS AND PALLADIUM (0) CATALYSIS

DOI: 10.1016/S0040-4039(00)97562-2

Source and publish data:

Tetrahedron Letters p. 4135 - 4138 (1990)

Update date:2022-09-26

Topics:

Authors:

Ollivier, Jean

Legros, Jean-Yves

Fiaud, Jean-Claude

Meijere, Armin de

Salauen, Jacques

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Article abstract of DOI:10.1016/S0040-4039(00)97562-2

While optically active (1-siloxycyclopropyl) allyl esters underwent ready Lewis acids induced rearrangement into 2-vinylcyclobutanone with chirality transfer up to 71.5percent, Pd(0) failed for stereoelectronic reason to catalyse the expected C-3 -> C-4 r

Full text of DOI:10.1016/S0040-4039(00)97562-2

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