Tetrahedron Letters p. 4135 - 4138 (1990)
Update date:2022-09-26
Topics:
Ollivier, Jean
Legros, Jean-Yves
Fiaud, Jean-Claude
Meijere, Armin de
Salauen, Jacques
While optically active (1-siloxycyclopropyl) allyl esters underwent ready Lewis acids induced rearrangement into 2-vinylcyclobutanone with chirality transfer up to 71.5percent, Pd(0) failed for stereoelectronic reason to catalyse the expected C-3 -> C-4 r
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