Transition Metal Complexes of Troeger's Base and their Catalytic Activity for the Hydrosilylation of Alkynes

DOI: 10.1016/0040-4039(94)02272-D

Source and publish data:

Tetrahedron Letters p. 369 - 372 (1995)

Update date:2022-08-02

Topics:

Authors:

Goldberg, Yuri

Alper, Howard

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Article abstract of DOI:10.1016/0040-4039(94)02272-D

Rhodium(III) and iridium(III) complexes of Troeger's base (TB), of structural type TB*2MCl3 (M=Rh, Ir), were prepared by treatment of TB with MCl3.The rhodium complex readily catalyzed the hydrosilylation of alkynes with high regio- and stereoselectively observed in some cases.

Full text of DOI:10.1016/0040-4039(94)02272-D

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