Iron-mediated Synthesis of Homochiral 4-Methylcyclohexenone Derivatives from p-Menthoxytoluene

DOI: 10.1039/c39900001172

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1172 - 1174 (1990)

Update date:2022-08-03

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Authors:

Potter, Gerard A.

McCague, Raymond

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Article abstract of DOI:10.1039/c39900001172

The tricarbonyl(2-menthoxy-5-methylcyclohexadienylium)iron hexafluorophosphate (4) prepared from p-menthoxytoluene can be obtained as a single diastereoisomer and displays excellent regioselectivity with a model nucleophile providing a route to homochiral 4-substituted 4-methylcyclohex-2-enones; other related homochiral synthons are also prepared.

Full text of DOI:10.1039/c39900001172

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