Journal of the Chemical Society. Chemical communications p. 503 - 504 (1988)
Update date:2022-09-26
Topics:
Verlhac, Jean-Baptiste
Quintard, Jean-Paul
Pereyre, Michel
Palladium-catalysed cross-coupling of a new umpolung reagent, (α-methoxy-γ-tributylstannyl)allyltrimethyl-silane, with acyl or aryl halides, involves exclusively the vinyl-tin bond and subsequent desilylation with tetrabutylammonium fluoride gives enol ethers, precursors of β-acyl- or β-aryl-propionaldehydes.
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