ARYLATION OF 1-TRIBUTYLSTANNYL GLYCALS CATALYZED BY PALLADIUM: A SYNTHETIC ROUTE TO THE BASIC SKELETON OF THE PAPULACANDINS AND CHAETIACANDIN

DOI: 10.1016/S0040-4039(00)97832-8

Source and publish data:

Tetrahedron Letters p. 5165 - 5168 (1990)

Update date:2022-07-29

Topics:

Authors:

Dubois, Eric

Beau, Jean-Marie

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Article abstract of DOI:10.1016/S0040-4039(00)97832-8

The palladium-catalyzed coupling reaction of 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-1-tri-n-butylstannyl-D-glucal 7 with 3,5-dibenzyloxy-2-bromo-benzyl alcohol 8 gave a 78percent yield of the C-arylated glycal 11, stereoselectivity transformed into

Full text of DOI:10.1016/S0040-4039(00)97832-8

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