Compactin from hajos (-)-enedione

DOI: 10.1016/S0040-4039(00)97906-1

Source and publish data:

Tetrahedron Letters p. 5599 - 5602 (1990)

Update date:2022-07-29

Topics: Compactin

Authors:

Daniewski

Uskokovi

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Article abstract of DOI:10.1016/S0040-4039(00)97906-1

Starting from easily accessible (-)-enedione 8, the hexahydronaphthalene part of compactin 1 was synthesized. The most important steps of this synthesis are: reductive alkylation of 8, cyclization of iodide 12 with SmI₂ and Zn, and regiospecifi

Full text of DOI:10.1016/S0040-4039(00)97906-1

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Product name:(S)-1-<(3aR,7S,7aR)-3a-methyl-3,6-dioxohexahydroindan-7-yl>-4-<<(4-methylphenyl)sulfonyl>oxy>butan-1-ol acetate

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