Tetrahedron p. 6423 - 6432 (1990)
Update date:2022-08-02
Topics:
Iqbal, Javed
Pandey, Anu
Shukla, Alka
Srivastava, Rajiv Ranjan
Tripathi, Sanjay
: Oxiranes are regioselectively cleaved by benzenethiol in presence of cobalt(II) chloride or Co2(CO)8 to the corresponding β-hydroxy sulfides in good yields. A mechanistic study of this reaction reveals that an electron transfer process is involved in these transformations and the reaction is proceeding via the formation of a carbon-cobalt bond.
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