Helvetica Chimica Acta p. 1719 - 1723 (1990)
Update date:2022-08-02
Topics:
Nishio, Takehiko
Okuda, Norikazu
Kashima, Choji
Reduction of indolin-2-ones with lithium aluminium hydride (LAH) or diisobutylaluminium hydride (DIBAL) and desulfurization of indoline-2-thiones with Raney-Ni were investigated.Treatment of indolin-2-ones 1 with LAH or DIBAL yielded indoles 4 and/or indolines 3 in moderate-to-high yields depending on the substituents at N and C(3) of 1.Indoline-2-thiones 2 were desulfurized with Raney-Ni tigive indoles 4 and/or indolines 3.
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