Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1854 - 1861 (1990)
Update date:2022-08-04
Topics:
Dzhemilev, U. M.
Baibulatova, N. Z.
Kunakova, R. V.
Tkachenko, T. K.
Tolstikov, G. A.
The feasibility of the one-step synthesis of mixtures of Z- and E-alkenyl alkyl sulfides via the reaction of elemental sulfur with terminal and disubstituted alkynes and alkyl halides has been demonstrated in the presence of low-valent Ni, Co, Pd, and Fe complexes.The effects of structure in the starting alkynes and alkyl halides have been investigated, along with process conditions and their effect on the composition and yields of reaction products.
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