ASYMMETRIC SYNTHESIS OF (R) AND (S)-4-HYDROXY-2-CYCLOHEXENONE AND DERIVATIVES

DOI: 10.1016/S0040-4039(00)97138-7

Source and publish data:

Tetrahedron Letters p. 6653 - 6656 (1990)

Update date:2022-07-30

Topics:

Authors:

Carreno, M. Carmen

Ruano, Jose L. Garcia

Garrido, Mercedes

Ruiz, M. Pilar

Solladie, Guy

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Article abstract of DOI:10.1016/S0040-4039(00)97138-7

The asymmetric syntheses of both enantiomers of 4-hydroxy-2-cyclohexenone and their O-acyl and O-benzyl derivatives are reported.DIBAL and ZnCl2/DIBAL stereoselective reductions of the ketosulfoxides resulting in the sulfinylation of 1,4-cyclohexanedione

Full text of DOI:10.1016/S0040-4039(00)97138-7

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