Helvetica Chimica Acta p. 1135 - 1142 (1991)
Update date:2022-08-02
Topics:
Giese, Bernd
Thoma, Gebhard
Irradiation of dicarbonyl(η5-cyclopentadienyl)iron dimer 1 or decacarbonyldimanganese (2) in the presence of alkyl halides leads to C-centered radicals which can be trapped by alkenes and yields saturated and/or unsaturated addition products.Carbon radicals are generated via halogen abstraction by the initially formed metal-centered radicals resulting from homolysis of the metal-metal bond of dimeric mediators 1 and 2.No reaction occurs using octacarbonyl dicobalt (3).
View MoreXian Changyue Biological Technology Co., Ltd.
website:https://www.xachangyue.com/
Contact:+86-029-88211911
Address:Keji Road NO.70
Contact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Pengchen New Material Technology Co., Ltd.
Contact:+86-512-63680537
Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Doi:10.1016/j.tet.2007.01.018
(2007)Doi:10.1055/s-0030-1260568
(2011)Doi:10.1002/ejoc.201100628
(2011)Doi:10.1016/S0040-4039(00)88566-4
(1990)Doi:10.1002/jhet.5570270712
(1990)Doi:10.1002/asia.201100277
(2011)
