Synthesis and electrochemical properties of the unknown N,N-bisheteroaryl amines bearing a fused heterocycle as N-substituent

Article abstract of DOI:10.1016/S0040-4039(00)97029-1

The first preparation of N,N-bisheteroaryl amines bearing a fused heterocycle as N-substituent, from the iminophosphorane derived from 3-amino-4-phenylthiazoline-2(3H)-thione by sequential treatment with alkyl isocyanates and tetrafluoroboric acid is described. Its electrochemical behaviour shows that these compounds can act as organic electron transfer agents in indirect electrolysis.