Journal of Organometallic Chemistry p. 205 - 214 (1993)
Update date:2022-09-26
Topics:
Brunet, Jean-Jacques
Gomez, Montserrat
Hajouji, Hassane
Neibecker, Denis
An improved, 90percent yield synthesis of the chiral diphosphole, (R,R)-DIPPOP (1) is reported.The reactions of 1 with nickel, palladium, platinum and rhodium complexes are examined. 1 does not react with NiCl2.With PdCl2 and PtCl2, it forms various cis and trans diphosphine-bridged cyclooligomers of undetermined ring size.The rhodium complexes
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