Tetrahedron Letters p. 137 - 140 (1991)
Update date:2022-08-04
Topics:
Baraniak
Stec
2-N-Benzoyl-N-phenylamino-2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinane (3a) undergoes rearrangement to (2-oxo-5,5-dimethyl-1,3,2-dioxaphosphorinanyl) (N-phenyliminobenzoyl)oxide (4a). This transformation is shown to be catalysed by electrophilic reagents such as benzoyl chloride, trimethylsilyl chloride, p-toluenesulphonyl chloride.
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