Journal of Organic Chemistry p. 4158 - 4164 (1989)
Update date:2022-08-03
Topics:
Arjona, Odon
Pradilla, Roberto Fernandez de la
Mallo, Araceli
Perez, Sonia
Plumet, Joaquin
The reaction between 7-oxabicyclo<2.2.1>hept-5-en-2-one and a variety of organolithium, Grignard, and organocuprate reagents is described.Organolithium and Grignard reagents yield the expected endo alcohols with high selectivity.Alternatively, lithium organocuprates add with high stereoselectivity to the hindered endo face of the carbonyl functionality to afford the corresponding exo alcohols.
View MoreContact:+86 21 5017 5386
Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
website:http://www.chinabarton.com
Contact:+86-573-82719618
Address:No. 162 Fumin Road, Honghe Town,
Changzhou Welton Chemical Co., Ltd,
Contact:0086-519-85910828,85920537,85912897
Address:No.8 Jinlong Road, Binjiang Park, Changzhou, Jiangsu, China.
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Nanjing Chemzam Pharmtech Co., Ltd.
Contact:+86-25-86462165,+86-13915979898
Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
Doi:10.1002/chem.201003744
(2011)Doi:10.1002/asia.201800134
(2018)Doi:10.1021/ol201600s
(2011)Doi:10.1039/c1cc13348a
(2011)Doi:10.1021/ol301946r
(2012)Doi:10.1002/anie.201102562
(2011)
