Chemical Communications p. 9456 - 9458 (2011)
Update date:2022-08-03
Topics:
Jimenez-Aquino, Agustin
Ferrer Flegeau, Emmanuel
Schneider, Uwe
Kobayashi, Shu
We developed catalytic intermolecular C(sp3)-C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
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