Chemistry - A European Journal p. 9571 - 9575 (2011)
Update date:2022-08-05
Topics:
Tejedor, David
Lopez-Tosco, Sara
Gonzalez-Platas, Javier
Garcia-Tellado, Fernando
Diverting is the game! A new domino manifold has been implemented for the synthesis of cyclohexadienone-based scaffolds from tertiary skipped diynes and secondary amines. The manifold takes advantage of a new O-enolate-driven reactivity pattern discovered for these diynes. The scaffolds are conveniently transformed into the corresponding multivalent salicylate derivatives (see scheme).
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