Tris-aza-cope rearrangement of bicyclic N-cyano-N'-vinyl or N'-arylhydrazines to imidazolo-diazepine derivatives

DOI: 10.1016/S0040-4039(00)92117-8

Source and publish data:

Tetrahedron Letters p. 907 - 910 (1991)

Update date:2022-08-05

Topics:

Authors:

Rousselle

Musick Musick

Viehe Viehe

Tinant Tinant

Declercq

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Article abstract of DOI:10.1016/S0040-4039(00)92117-8

The bicyclic N-cyanohydrazines 6 and 12 undergo smoothly an unusual isomerisation to the new imidazole-diazepines 9 and 15. The X-ray analysis of structure 9b is reported.

Full text of DOI:10.1016/S0040-4039(00)92117-8

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