An efficient synthetic pathway to the macroline-type indole alkaloids, talcarpine and alstonerine from ajmaline

DOI: 10.1016/S0040-4020(01)86414-0

Source and publish data:

Tetrahedron p. 1383 - 1392 (1991)

Update date:2022-08-04

Topics:

Authors:

Takayama, Hiromitsu

Phisalaphong, Chada

Kitajima, Mariko

Aimi, Norio

Sakai, Shin-Ichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86414-0

Ajmaline (6) was transformed into two macroline-related indole alkaloids, talcarpine (1) and alstonerine (2) via the common synthetic intermediate (13). The stereochemistry at C19 position in talcarpine (1) and talpinine (5) were elucidated by NOE experim

Full text of DOI:10.1016/S0040-4020(01)86414-0

Products guided by the article

Product name:Carbonic acid benzyl ester (3S,4R,8S,13aR)-3-ethyl-8-hydroxy-13-methyl-1,3,4,7,8,13,13a,13b-octahydro-2H,6H-2,7-cyclo-6,8a-methano-pyrido[1',2':1,2]azepino[3,4-b]indol-4-yl ester

Cas No:133761-67-8

R&D Labs maybe for 133761-67-8

Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Quzhou Aokai Chemical Co., Ltd.

Contact:86-570-3032832

Address:NO.16 , Laodong Road,Quzhou City, Zhejiang Province,China

Relevant to this article

Synthesis and photoluminescence of Zinc(II) complexes with tetrafluoroterephthalic acid (H₂L). Crystal structure of coordination polymer [Zn(H₂O)₄(L) ? 4H₂O] _n

Doi:10.1134/S1070328411090041
(2011)
Synthesis of 3,7-disubstituted imipramines by palladium-catalysed amination/cyclisation and evaluation of their inhibition of monoamine transporters

Doi:10.1002/chem.201100885
(2011)
Solvent-free synthesis of hydrazones and their subsequent N-alkylation in a Ball-mill

Doi:10.1016/j.tet.2011.07.056
(2011)
Efficient indoles and anilines syntheses employing tert-butyl sulfinamide as ammonia surrogate

Doi:10.1016/j.tetlet.2011.08.075
(2011)
Effektive Transformation of Unactivated Alkynes into Ketones or Acetals by Means of Au(III) Catalyst

Doi:10.1021/jo00011a058
(1991)
The diastereoselective formation of tetraalkoxy[4]resorcinarenes derived from (-)-(2R)-2-methoxy-2-phenylethanol and proof of absolute configurations

Doi:10.1002/ejoc.201100733
(2011)

Article Doi