Phosphorus, Sulfur and Silicon and the Related Elements p. 53 - 62 (2018)
Update date:2022-07-29
Topics:
Mironov, Vladimir F.
Ivkova, Gulnara A.
Abdrakhmanova, Liliya M.
Musin, Rashid Z.
Mironova, Ekaterina V.
Krivolapov, Dmitry B.
Gubaidullin, Aidar T.
The interaction of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphinin-4-one with mesoxalic and trifluoropyruvic acids ethyl and diethyl esters, hexafluoroacetone and chloral proceeds with an exclusive participation of P(III) atom and allows to obtain 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-derivatives of 1,4,2- and 1,3,2-dioxaphosphepines as well as dichlorovinylphosphonate, being the product of Perkow reaction in the case of chloral.
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