Formation of α--Substituted Stable Enols and N,N-Dialkyldiarylacetamides from Diarylketenes and MeLi in HMPA

DOI: 10.1021/jo00013a031

Source and publish data:

Journal of Organic Chemistry p. 4241 - 4246 (1991)

Update date:2022-08-05

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Authors:

Nadler, Ella B.

Zipory, Elana S.

Rappoport, Zvi

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Article abstract of DOI:10.1021/jo00013a031

The reaction of an MeLi/HMPA mixture in ether with dimesityl- and mesitylphenylketene yielded the enols MesC(Ar)=C(OH)PO(NMe2)2 and MesC(Ar)=CHOH and the amides MesCH(Ar)CON(Me)R (Ar = Mes, Ph; R = Me, Et) together with other products.An initial cleavage

Full text of DOI:10.1021/jo00013a031

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