Carbopalladation of functionalized allenes: Regioselectivity of the reaction of carbonucleophiles with the intermediate π-allyl palladium complexes

DOI: 10.1016/S0040-4039(00)74332-2

Source and publish data:

Tetrahedron Letters p. 1795 - 1798 (1991)

Update date:2022-08-03

Topics:

Authors:

Chaptal Chaptal

Colovray-Gotteland

Grandjean

Cazes Cazes

Gore Gore

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74332-2

Carbopalladation of functionalized allenes leads to π-allyl palladium complexes, the regiochemistry of which towards carbonucleophiles has been studied: a methoxy group has been demonstrated to reverse the classical regioselectivity and to allow the forma

Full text of DOI:10.1016/S0040-4039(00)74332-2

Products guided by the article

Product name:2-{2-[1-Phenyl-meth-(Z)-ylidene]-but-3-enyl}-malonic acid diethyl ester

Cas No:134600-37-6

R&D Labs maybe for 134600-37-6

Li's chemicals

Contact:+86-15850770348

Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
SHANXI XINTIANYUAN PHARMACEUTICAL CO., LTD.

website:http://www.tychemical.com

Contact:0086-358-3521713 3521715

Address:No. 1 Yintong Road, Shanxi Jiaocheng Economic Development Zone, Xiajiaying Town, Jiaocheng County, Lvliang City, Shanxi Province, China

Relevant to this article

Heteroscorpionate rare-earth metal zwitterionic complexes: Syntheses, characterization, and heteroselective catalysis on the ring-opening polymerization of rac-lactide

Doi:10.1002/chem.201102074
(2011)
Three-step metal-promoted allene-based preparation of Bis(heterocyclic) cyclophanes from carbonyl compounds

Doi:10.1021/jo500993x
(2014)
Tandem palladium/charcoal-copper(I) iodide (Pd/C-CuI) catalyzed Sonogashira coupling and intramolecular cyclization from 2-bromonicotinic acid (=2-bromopyridine-3-carboxylic acid) and ethynylarenes to 4-azaphthalides (=furo[3,4-b]pyridin-5(7H)-ones) and 5-azaisocoumarins (=5H-pyrano[4,3-b] pyridin-5-ones)

Doi:10.1002/hlca.201100060
(2011)
Total synthesis of (-)-indolizidine 239CD

Doi:10.1039/c39910000405
(1991)
Total synthesis of the macrodiolide pyrenophorol

Doi:10.1016/0040-4039(91)80368-G
(1991)
Bifunctional 3, 3′-Ph₂-BINOL-Mg catalyzed direct asymmetric vinylogous michael addition of α, β-unsaturated γ-butyrolactam

Doi:10.1021/ol202713f
(2011)

Article Doi