Carbopalladation of functionalized allenes: Regioselectivity of the reaction of carbonucleophiles with the intermediate π-allyl palladium complexes

DOI: 10.1016/S0040-4039(00)74332-2

Source and publish data:

Tetrahedron Letters p. 1795 - 1798 (1991)

Update date:2022-08-03

Topics:

Authors:

Chaptal Chaptal

Colovray-Gotteland

Grandjean

Cazes Cazes

Gore Gore

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74332-2

Carbopalladation of functionalized allenes leads to π-allyl palladium complexes, the regiochemistry of which towards carbonucleophiles has been studied: a methoxy group has been demonstrated to reverse the classical regioselectivity and to allow the forma

Full text of DOI:10.1016/S0040-4039(00)74332-2

Products guided by the article

Product name:2-{2-[1-Phenyl-meth-(Z)-ylidene]-but-3-enyl}-malonic acid diethyl ester

Cas No:134600-37-6

R&D Labs maybe for 134600-37-6

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
Chengdu Pukang Biotechnology Co., Ltd

website:http://www.pu-kang.com

Contact:86-028-63976226

Address:No. 868 Xiwang Road,Xinjin county,Chengdu city, China
Qingdao Pana-Life Biochem Co.,Ltd.

Contact:86-532-87683902

Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.

Relevant to this article

Heteroscorpionate rare-earth metal zwitterionic complexes: Syntheses, characterization, and heteroselective catalysis on the ring-opening polymerization of rac-lactide

Doi:10.1002/chem.201102074
(2011)
Three-step metal-promoted allene-based preparation of Bis(heterocyclic) cyclophanes from carbonyl compounds

Doi:10.1021/jo500993x
(2014)
Tandem palladium/charcoal-copper(I) iodide (Pd/C-CuI) catalyzed Sonogashira coupling and intramolecular cyclization from 2-bromonicotinic acid (=2-bromopyridine-3-carboxylic acid) and ethynylarenes to 4-azaphthalides (=furo[3,4-b]pyridin-5(7H)-ones) and 5-azaisocoumarins (=5H-pyrano[4,3-b] pyridin-5-ones)

Doi:10.1002/hlca.201100060
(2011)
Total synthesis of (-)-indolizidine 239CD

Doi:10.1039/c39910000405
(1991)
Total synthesis of the macrodiolide pyrenophorol

Doi:10.1016/0040-4039(91)80368-G
(1991)
Bifunctional 3, 3′-Ph₂-BINOL-Mg catalyzed direct asymmetric vinylogous michael addition of α, β-unsaturated γ-butyrolactam

Doi:10.1021/ol202713f
(2011)

Article Doi