Intramolecular Diels-Alder Reactions of 1-Thia-3-azabutadienes. One-Pot Synthesis of Annulated Thiazines from N-(Trimethylsilyl)imines and Isothiocyanates

DOI: 10.1021/jo00019a040

Source and publish data:

Journal of Organic Chemistry p. 5680 - 5684 (1991)

Update date:2022-08-02

Topics:

Authors:

Barluenga, Jose

Tomas, Miguel

Ballesteros, Alfredo

Lopez, Luis A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00019a040

The intramolecular <4+2> cycloaddition of 1-thia-3-aza dienes is described.Substituted N-(trimethylsilyl)imines 2 derived from aromatic and heteroaromatic aldehydes 1 react with isothiocyanates to form heterodienes 3, which, although not isolated, undergo

Full text of DOI:10.1021/jo00019a040

Products guided by the article

Product name:N-(trimethylsilyl)-2-(oxapent-3-enyl)benzylideneamine

Cas No:135192-05-1

R&D Labs maybe for 135192-05-1

shandong zhongke taidou chemical co.,ltd

Contact:86-531-88682301

Address:Jinan shandong Province CHina
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China

Relevant to this article

Systematic study on the catalytic synthesis of unsaturated 2-ketocarboxamides: Palladium-catalyzed double carbonylation of 1-iodocyclohexene

Doi:10.1016/j.tet.2011.10.065
(2012)
Activation of anisole by organoplatinum(II) complexes: Evidence for rate-determining C-H activation

Doi:10.1021/om200922a
(2012)
DBU-Mediated Synthesis of Aryl Acetylenes or 1-Bromoethynylarenes from Aldehydes

Doi:10.1002/adsc.201801334
(2019)
Two new acetylated flavonoid glycosides from Centaurium spicatum L

Doi:10.1007/s11418-011-0594-y
(2012)
Tailoring the specificity and reactivity of a mechanism-based inactivator of glucocerebrosidase for potential therapeutic applications

Doi:10.1002/anie.201103924
(2011)
Chiral dihydrobenzo[1,4]oxazines as catalysts for the asymmetric transfer-hydrogenation of α,β-unsaturated aldehydes

Doi:10.1016/j.tet.2011.10.051
(2011)

Article Doi