Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: Preparation of mono-, bi-, and tricyclic systems

DOI: 10.1039/c1ob06189e

Source and publish data:

Organic and Biomolecular Chemistry p. 56 - 59 (2012)

Update date:2022-08-03

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Authors:

Bennett, Nathan B.

Hong, Allen Y.

Harned, Andrew M.

Stoltz, Brian M.

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Article abstract of DOI:10.1039/c1ob06189e

A general method for the synthesis of β-substituted and unsubstituted cycloheptenones bearing enantioenriched all-carbon γ-quaternary stereocenters is reported. Hydride or organometallic addition to a seven-membered ring vinylogous ester followed by finel

Full text of DOI:10.1039/c1ob06189e

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