The Use of ?-Allyltricarbonyliron Lactone Complexes in the Synthesis of the β-Lactone Esterase Inhibitor (-)-Valilactone.

DOI: 10.1016/S0040-4020(01)80728-6

Source and publish data:

Tetrahedron p. 9929 - 9938 (1991)

Update date:2022-07-30

Topics:

Authors:

Bates, Roderick W.

Fernandez-Moro, Rosalina

Ley, Steven V.

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Article abstract of DOI:10.1016/S0040-4020(01)80728-6

A concise synthesis of the β-lactone esterase inhibitor valilactone (2) is reported.This synthesis employs the stereoselective preparation of a ?-allyltricarbonyliron lactone complex (7) that on oxidation with ceric ammonium nitrate, affords an appropriat

Full text of DOI:10.1016/S0040-4020(01)80728-6

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