Thiolate Complexes of Osmium(III) and Osmium(IV). Crystal Structures of and

DOI: 10.1039/DT9910001281

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1281 - 1284 (1991)

Update date:2022-08-04

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Authors:

Hills, Adrian

Hughes, David L.

Richards, Raymond L.

Arroyo, Maribel

Cruz-Garritz, Diana

Torrens, Hugo

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Article abstract of DOI:10.1039/DT9910001281

Treatment of (R = C6F5 or C6HF4) with PhCO2H or with HCl in acetone gives, respectively, the red paramagnetic osmium(III) derivatives 1 and the green, five-co-ordinate, diamagnetic osmium(IV) complexes 2.X-Ray crystallography has shown that 1 (R = C6F5) has an octahedral structure with trans-thiolates, cis-phosphines and a chelating benzoate ligand and that 2 (R = C6F5) has a trigonal-bipyramidal structure with thiolates in the equatorial plane.

Full text of DOI:10.1039/DT9910001281

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