Thiolate Complexes of Osmium(III) and Osmium(IV). Crystal Structures of and

DOI: 10.1039/DT9910001281

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1281 - 1284 (1991)

Update date:2022-08-04

Topics:

Authors:

Hills, Adrian

Hughes, David L.

Richards, Raymond L.

Arroyo, Maribel

Cruz-Garritz, Diana

Torrens, Hugo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910001281

Treatment of (R = C6F5 or C6HF4) with PhCO2H or with HCl in acetone gives, respectively, the red paramagnetic osmium(III) derivatives 1 and the green, five-co-ordinate, diamagnetic osmium(IV) complexes 2.X-Ray crystallography has shown that 1 (R = C6F5) has an octahedral structure with trans-thiolates, cis-phosphines and a chelating benzoate ligand and that 2 (R = C6F5) has a trigonal-bipyramidal structure with thiolates in the equatorial plane.

Full text of DOI:10.1039/DT9910001281

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Os(III)Cl(SC₆HF₄)3(PMe₂Ph)}

Cas No:135444-30-3

R&D Labs maybe for 135444-30-3

Chemtrade International ( China )

Contact:+86-532-86893005

Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
Jiangxi Global Natural Spice Co., Ltd.

website:https://www.jxhqxl.com/

Contact:+86-796-8106598

Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province

Relevant to this article

Kinetic resolution of fluorinated propargyl alcohols by lipase-catalyzed enantioselective transesterification

Doi:10.1016/j.tetasy.2009.03.041
(2009)
Rigid P-chiral phosphine ligands with tert -butylmethylphosphino groups for rhodium-catalyzed asymmetric hydrogenation of functionalized alkenes

Doi:10.1021/ja209700j
(2012)
Chromium-Catalyzed Regioselective Hydropyridination of Styrenes

Doi:10.1021/acs.organomet.5b01021
(2016)
Light fluorous synthesis of glucosylated glycerol teichoic acids

Doi:10.1016/j.carres.2012.02.023
(2012)
Synthesis, characterization, and crystal structures of 3-bromo-n′-(2- methoxybenzylidene)benzohydrazide and n′-(2-methoxybenzylidene)-3,4- methylenedioxybenzohydrazide

Doi:10.1007/s10870-011-9982-0
(2011)
Structure-Activity Relationships of Quinoxaline-Based 5-HT₃A and 5-HT₃AB Receptor-Selective Ligands

Doi:10.1002/cmdc.201300032
(2013)

Article Doi