Use of Sulfoxides as Cocatalysts in the Palladium-Quinone-Catalyzed 1,4-Diacetoxylation of 1,3-Dienes. An Example of Ligand-Accelerated Catalysis

DOI: 10.1021/jo00020a022

Source and publish data:

Journal of Organic Chemistry p. 5808 - 5811 (1991)

Update date:2022-07-30

Topics:

Authors:

Grennberg, Helena

Gogoll, Adolf

Baeckwall, Jan-E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00020a022

The use of sulfinyl quinones as cocatalysts in the palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes improves the stereochemical outcome of the reaction by increasing the rate of the internal migration of the acetate nucleophile.A mechansim of the int

Full text of DOI:10.1021/jo00020a022

Products guided by the article

Product name:1-(R)-(+)-(p-tolylsulfinyl)-2,5-dimethoxybenzene

Cas No:135615-67-7

R&D Labs maybe for 135615-67-7

WEIFANG RICHEM INTERNATIONAL LTD

Contact:86-536-2222176

Address:weifang,shandong
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP

Relevant to this article

A new dimension in cyclic coinage metal pyrazolates: Decoration with a second ring of coinage metals supported by inter-ring metallophilic interactions

Doi:10.1021/ja211549e
(2012)
2-C-Carbamoyl-, 2-C-cyano-, and 2-C-acetamidomethyl-substituted glycosides

Doi:10.1016/0008-6215(91)84067-O
(1991)
Synthesis of polysubstituted quinolines via transition-metal-free oxidative cycloisomerization of o -cinnamylanilines

Doi:10.1021/acs.orglett.5b00419
(2015)
Catalyst-free, aqueous and highly diastereoselective synthesis of new 5-substituted 1H-tetrazoles via a multi-component domino Knoevenagel condensation/1,3 dipolar cycloaddition reaction

Doi:10.1016/j.tet.2011.12.044
(2012)
Exception to the ortho effect in palladium/norbornene catalysis

Doi:10.1002/anie.201104356
(2011)
Synthesis of novel triazoles bearing 1,2,4-oxadiazole and phenylsulfonyl groups by 1,3-dipolar cycloaddition of some organic azides and their biological activities

Doi:10.3906/kim-1309-59
(2014)

Article Doi