Use of Sulfoxides as Cocatalysts in the Palladium-Quinone-Catalyzed 1,4-Diacetoxylation of 1,3-Dienes. An Example of Ligand-Accelerated Catalysis

DOI: 10.1021/jo00020a022

Source and publish data:

Journal of Organic Chemistry p. 5808 - 5811 (1991)

Update date:2022-07-30

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Authors:

Grennberg, Helena

Gogoll, Adolf

Baeckwall, Jan-E.

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Article abstract of DOI:10.1021/jo00020a022

The use of sulfinyl quinones as cocatalysts in the palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes improves the stereochemical outcome of the reaction by increasing the rate of the internal migration of the acetate nucleophile.A mechansim of the int

Full text of DOI:10.1021/jo00020a022

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