Asymmetric Synthesis of Trisubstituted gem-Difluorocyclohexanes by Intramolecular Trapping of Difluoroalkyl Radicals.

DOI: 10.1016/S0957-4166(00)82161-8

Source and publish data:

Tetrahedron Asymmetry p. 399 - 402 (1991)

Update date:2022-07-29

Topics:

Authors:

Arnone, Alberto

Bravo, Pierfrancesco

Viani, Fiorenza

Cavicchio, Giancarlo

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Article abstract of DOI:10.1016/S0957-4166(00)82161-8

gem-Difluorocyclohexanols 8 bearing a methyl and a p-tolyl-sulphinyl substituent have been synthesized in optically pure form by intramolecular trapping of difluoroalkyl radicals on terminal double bonds.The radical intermediates have been generated by th

Full text of DOI:10.1016/S0957-4166(00)82161-8

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