Asymmetric Synthesis of Trisubstituted gem-Difluorocyclohexanes by Intramolecular Trapping of Difluoroalkyl Radicals.

DOI: 10.1016/S0957-4166(00)82161-8

Source and publish data:

Tetrahedron Asymmetry p. 399 - 402 (1991)

Update date:2022-07-29

Topics:

Authors:

Arnone, Alberto

Bravo, Pierfrancesco

Viani, Fiorenza

Cavicchio, Giancarlo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(00)82161-8

gem-Difluorocyclohexanols 8 bearing a methyl and a p-tolyl-sulphinyl substituent have been synthesized in optically pure form by intramolecular trapping of difluoroalkyl radicals on terminal double bonds.The radical intermediates have been generated by th

Full text of DOI:10.1016/S0957-4166(00)82161-8

Products guided by the article

Product name:(1S,3R,6R,R_S)-2,2-Difluoro-3-methyl-6-<(4-methylphenyl)sulfinyl>cyclohexanol

Cas No:136310-17-3

R&D Labs maybe for 136310-17-3

Shanghai Mintchem Development ., Ltd

Contact:0086 21 5190 8570

Address:R602,4#,89Nong, Mudan Road Pudong Shanghai China
Changsha Easchem Co.,Limited

website:http://www.easchem.com

Contact:+86-731-89722861 89722891

Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Hefei EnliPharma Tecnology Co.,Ltd

Contact:0086-551-66399836

Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei

Relevant to this article

Reaction of enaminones with benzyltrimethylammonium dichloroiodate

Doi:10.1248/cpb.42.1149
(1994)
Partial halogenation of cyclic and branched perhydropentasilanes

Doi:10.1021/ic300214y
(2012)
Sulfinyl-mediated stereoselective overman rearrangements and Diels-Alder cycloadditions

Doi:10.1021/ol301139a
(2012)
Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis

Doi:10.1021/ja303116v
(2012)
A moisture- and air-stable cationic ruthenium complex as catalyst for highly atom-economical stereo- and regioselective vinylation of azoles

Doi:10.1002/chem.201103424
(2012)
Facile isocyanide-based one-pot three-component regioselective synthesis of highly substituted pyridin-2(1H)-one derivatives at ambient temperature

Doi:10.1016/j.tet.2012.03.124
(2012)

Article Doi