Synthesis of optically active cyclohexenol derivatives via enzyme catalyzed ester hydrolysis of 4-acetoxy-3-methyl-2-cyclohexenone

DOI: 10.1016/S0040-4020(01)86539-X

Source and publish data:

Tetrahedron p. 5883 - 5894 (1991)

Update date:2022-08-03

Topics:

Authors:

Polla, Magnus

Frejd, Torbjoern

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Article abstract of DOI:10.1016/S0040-4020(01)86539-X

The optically active cyclohexenol derivatives 9a-9d, and 10a-10c are synthesized from (-)-6, which is obtained by enzymatic ester hydrolysis of racemic 8. Attempts towards the synthesis of the taxane skeleton are described.

Full text of DOI:10.1016/S0040-4020(01)86539-X

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Product name:(S)-4-<(t-butyldiphenylsilyl)oxy>-3-methyl-2-cyclohexenone

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