Cobalt-Catalyzed Photochemical Carbonylation of Allylic Amines

DOI: 10.1246/cl.1991.1397

Source and publish data:

Chemistry Letters p. 1397 - 1400 (1991)

Update date:2022-08-03

Topics: Isolation and Purification Reaction Mechanism Photocatalysis Carbon Monoxide (CO) Cobalt Catalyst Allylic Amines

Authors:

Mori, Sadayuki

Matsuyoshi, Hiroaki

Kudo, Kiyoshi

Sugita, Nobuyuki

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Article abstract of DOI:10.1246/cl.1991.1397

Allylic amines are carbonylated at room temperature in the presence of cobalt catalysts under UV irradiation.With allylamine, 2-pyrrolidone, N,N'-diallylurea, and N-allyl-3-butenamide were obtained.The photochemical cleavage of C-N bond of amines coordinated to cobalt metals was suggested.

Full text of DOI:10.1246/cl.1991.1397

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