Chemistry Letters p. 1397 - 1400 (1991)
Update date:2022-08-03
Topics: Isolation and Purification Reaction Mechanism Photocatalysis Carbon Monoxide (CO) Cobalt Catalyst Allylic Amines
Mori, Sadayuki
Matsuyoshi, Hiroaki
Kudo, Kiyoshi
Sugita, Nobuyuki
Allylic amines are carbonylated at room temperature in the presence of cobalt catalysts under UV irradiation.With allylamine, 2-pyrrolidone, N,N'-diallylurea, and N-allyl-3-butenamide were obtained.The photochemical cleavage of C-N bond of amines coordinated to cobalt metals was suggested.
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