Regiochemical Control of the Ring-Opening of 1,2-Epoxides by Means of Chelating Processes. 3. Aminolysis and Azidolysis of the cis- and trans-Oxides Derived from 4-(Benzyloxy)cyclohexene

Article abstract of DOI:10.1021/jo00025a018

The previously observed regiocontrol of the ring-opening of epoxides bearing a remote polar group such as the title compounds (1 and 2) can also be achieved by metal-assisted methods for the direct aminolysis and azidolysis of epoxides.The appropriate use